Is Ba(OH)2 weak base or strong base? - Barium hydroxide

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is barium hydroxide (Baoh2) Strong base or weak base?

Barium hydroxide is white in color appears as a granular solid that has no odor with the chemical formula Ba(OH)2. It is also known as baryta. It is slightly soluble in cold water and is mainly used for the production of barium-related compounds.

 In this article, we will discuss Is Barium hydroxide (BaOH2) strong or weak base? 

So, Is Ba(OH)2 strong base or a weak base? Ba(OH)2 is a strong base because on dissolving in an aqueous solution, it completely dissociates into two ions(Ba2+ and 2OH), the presence of a large number of OH ions in the aqueous solution of Ba(OH)2 makes it basic in nature.

Name of MoleculeBarium hydroxide
Chemical formulaBa(OH)2
pH valueAround 11
NatureStrong base
Basicity (pKb)0.15 (first OH), 0.64 (second OH)

Why Ba(OH)2 is strong base?

To know whether Ba(OH)2 is a strong base or weak, you must know the basic difference between a strong base or a weak base.

Strong base: A compound is a strong base when it completely dissociates in an aqueous solution and liberates a large number of hydroxide ions. All moles of the strong base dissociates into hydroxide ions(OH) and no part remains undissociated inside the solution.

Example: Sodium hydroxide(NaOH), Calcium hydroxide (Ca(OH)2), Lithium hydroxide (LiOH), Potassium hydroxide (KOH), etc.

Also Read:-

Weak base: A compound is a weak base when it partially or not completely dissociate in an aqueous solution which means not all moles of the base dissociate in a solution to yield OH ion, and at equilibrium, both undissociated base and their ionized product present in the solution. 

Example- Ammonia (NH3), Methylamine (CH3NH2), NH4OH, etc.

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Strong baseWeak base
They ionize completely.They do not completely ionize.
They are highly reactive.They are less reactive compare to a strong base.
The value of pH lies between 10 to 14.The value of pH lies between 7 to 10.
They have a high equilibrium constant.They have a less equilibrium constant.
They are good electrolytes.They are not so good electrolytes compare to a strong base.
Example – NaOH, KOH, LiOH, etc. Example – N2H4, NH3, NH4OH, etc.

So, Why Barium hydroxide Ba(OH)2 is a strong base? Ba(OH)2 is the strong base because it completely dissociates in an aqueous solution to give OH ion and no moles of it remain undissociated inside the solution. And the amount of OH ions in an aqueous solution is very high and we know OH ions have a tendency to accept the proton.

So, more proton acceptors present in the solution ultimately make Ba(OH)2 a strong base.

why Ba(OH)2 is strong base

As you see in the above aqueous solution when Ba(OH)2 is dissolved in water, it is completely ionized into the ions(Ba2+ and 2OH). No undissociated molecule(Ba(OH)2) is present in the solution, only ionized ions are present everywhere in the solution.

The single arrow used in the above reaction shows that only forward reaction takes place at equilibrium and no backward reaction occurs in solution.

As Ba2+ is a very weak conjugate acid of Ba(OH)2, hence it has no ability to react with either OH ion or with water molecules ions. Thus, only splitting ions(Ba2+ and 2OH) remain in the solution.

Or you can also assume the Ba2+ as a spectator ion because it is almost useless in solution, it has no effect on the pH value of the solution.

“A spectator ion is an ion that does not take part in the chemical reaction and is found in solution both before and after the reaction.”

Hence, a large number of hydroxide ions present in the aqueous solution of Ba(OH)2, steadily increase the pH value and rises the effect of the basic in solution.

Also, the base dissociation constant value(Kb) for Ba(OH)2 is larger than 1.

An base dissociation constant (Kb) is a quantitative measure of the strength of an base in solution.

⇒ If the value of the dissociation constant of the base is greater than 1 (Kb > 1), then the nature of the compound is a strong base.

⇒ If Kb < 1, then the nature of the compound is a weak base.

So, the higher the value of the base dissociation constant, the larger is the strength of a base in solution.

Here’s the list of some common strong/weak acids and bases.

is ba(oh)2 strong base or weak base?

Also check:- How to know if the base or acid is strong or weak?

How to know if Ba(OH)2 is acid or base practically?

To know if compound acid or base practically, one of the easiest ways to use litmus paper.

Litmus is a water-soluble mixture of different dyes extracted from lichens. It is often absorbed onto filter paper to produce one of the oldest forms of pH indicator, used to test materials for acidity. [Wiki]

Note: When Red litmus paper turns blue then the compound is said to be base. And when blue litmus paper turns red then the compound is said to be acidic.

When Ba(OH)2 is contacted with red litmus paper then litmus paper turns into blue color. So, we can say Ba(OH)2 is the base.

Is Ba(OH)2 alkali or not?

Alkali is a strong base that produces hydroxide ions when it is dissolved in water. All soluble hydroxides like lithium, cesium, sodium, potassium, etc. are alkali metals.

An alkali is said to be strongest when it produces almost all OH ions when it is dissolved in water. As Ba(OH)2 molecule, when dissolved in water produce almost all OH ions that ultimately make it strong alkali.

Uses of Barium hydroxide

  • It is used as the precursor to other barium compounds.
  • It is used in the manufacture of barium soaps and other barium compounds.
  • It is used to measure the concentration of weak acids.
  • It is also used in the treatment of sewage water.
  • It is used in organic synthesis as a strong base.

Properties of Barium hydroxide

  1. It is white in color and appears as a granular solid.
  2. It has a boiling point of 780 °C and a melting point of 78 °C.
  3. It has an octahedral crystal structure.
  4. It is non-flammable.
  5. The pH of Barium Hydroxide is around 11.

Summary

  • Is Ba(OH)2 acid or base? Ba(OH)2 is base, not an acid because it dissociates into OH ions in an aqueous solution which quickly absorbs H+ and forms water molecule, and, according to the Arrhenius theory, the compound is said to be base when it produces OH ion through ionization or through dissociation in water and increases the concentration of OH ions in an aqueous solution
  • Is Ba(OH)2 weak or strong base? Ba(OH)2 is the strong base as it completely dissociates in an aqueous solution and produces a higher amount of OH ions.
  • Barium hydroxide in an aqueous solution can provide two hydroxide ions per molecule.
  • The base dissociation constant value for Ba(OH)2 is larger than 1.
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